Palladium(II,IV) fluoride
-fluoride-xtal-2001-without-Pd(II)-F-bonds-CM-3D-balls.png) |
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| Names | |
|---|---|
| Other names
palladium(II) hexafluoropalladate(IV)
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| Identifiers | |
| Properties | |
| F3Pd | |
| Molar mass | 163.42 g·mol−1 |
| Appearance | black solid |
| +1760.0·10−6 cm3/mol | |
| Structure | |
| rhombohedral | |
| octahedral | |
| Related compounds | |
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Other cations
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Nickel(III) fluoride |
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Related compounds
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Palladium(II) fluoride Palladium(IV) fluoride |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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| Infobox references | |
Palladium(II,IV) fluoride, also known as palladium trifluoride, is a chemical compound of palladium and fluorine. It has the empirical formula PdF3, but is better described as the mixed-valence compound palladium(II) hexafluoropalladate(IV), PdII[PdIVF6] and is often written as Pd[PdF6] or Pd2F6.
Pd[PdF6] is the most stable product of the reaction of fluorine and metallic palladium.
Pd[PdF6] is paramagnetic and both Pd(II) and Pd(IV) occupy octahedral sites in the crystal structure. The PdII-F distance is 2.17 Å, whereas the PdIV-F distance is 1.90 Å.
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