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Cyclopentasiloxane

Decamethylcyclopentasiloxane
Skeletal formula of decamethylcyclopentasiloxane
Space-filling model of the decamethylcyclopentasiloxane molecule
Names
IUPAC name
Decamethyl-1,3,5,7,9,2,4,6,8,10-pentaoxapentasilecane
Other names
Cyclopentamethicone

Cyclic dimethylsiloxane pentamer
D5

2,2,4,4,6,6,8,8,10,10-Decamethylcyclopentasiloxane
Identifiers
3D model (Jmol)
1800166
ChemSpider
ECHA InfoCard 100.007.969
EC Number 208-764-9
MeSH Decamethylcyclopentasiloxane
PubChem CID
RTECS number GY5945200
UNII
Properties
C10H30O5Si5
Molar mass 370.77 g·mol−1
Appearance Colourless liquid
Density 0.958 g cm−3
Melting point −47 °C; −53 °F; 226 K
Boiling point 210 °C (410 °F; 483 K)
17.03±0.72 ppb (23 °C)
Vapor pressure 20.4±1.1 Pa (25 °C)
Viscosity 3.74 cP
Hazards
Safety data sheet External MSDS
Irritant Xi
R-phrases R36/37/38
S-phrases S23, S24/25
NFPA 704
Flammability code 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g., diesel fuel Health code 1: Exposure would cause irritation but only minor residual injury. E.g., turpentine Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
Flash point 73 °C (163 °F; 346 K)
Related compounds
Octamethylcyclotetrasiloxane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
YesY  (what is YesYN ?)
Infobox references

Cyclic dimethylsiloxane pentamer
D5

Decamethylcyclopentasiloxane (D5) is an organosilicon compound with the formula [(CH3)2SiO]5. It is a colorless and odorless liquid that is slightly volatile. The compound is classified as a cyclomethicone. Such fluids are commonly used in cosmetics, such as deodorants, sunblocks, hair sprays and skin care products. It is becoming more common in hair conditioners, as it makes the hair easier to brush without breakage. It is also used as part of silicone based personal lubricants. D5 is considered an emollient. In Canada, among the volume used in consumer products approximately 70% were for antiperspirants and 20% for hair care products.

Commercially D5, is produced by cracking polysiloxanes. The silicone polymer equilibrated in the presence of strong base to give the pentamer:

The tetramer octamethylcyclotetrasiloxane is also generated. These two cyclic species are separated from the polymer by distillation.

D5 and D4 have attracted attention because they are pervasive. Although never reported as being toxic, one report suggests cyclic siloxanes can be detected in some species of aquatic life. However, other scientific reviews have determined that "Siloxane D5 does not pose a danger to the environment."


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