Iron-45

Main isotopes of iron

Iso­tope Decay abun­dance half-life (t1/2) mode pro­duct 54Fe 5.85% stable 55Fe syn 2.73 y ε 55Mn 56Fe 91.75% stable 57Fe 2.12% stable 58Fe 0.28% stable 59Fe syn 44.6 d β− 59Co 60Fe syn 2.6×106 y β− 60Co
Standard atomic weight (Ar, standard)	55.845(2)

Naturally occurring iron (₂₆Fe) consists of four stable isotopes: 5.845% of ⁵⁴Fe (possibly radioactive with a half-life over 3.1×10²² years), 91.754% of ⁵⁶Fe, 2.119% of ⁵⁷Fe and 0.282% of ⁵⁸Fe. There are 24 known radioactive isotopes and their half-lives are shown below. See Brookhaven National Laboratory Interactive Table of Nuclides for a more accurate reading.

Much of the past work on measuring the isotopic composition of Fe has centered on determining ⁶⁰Fe variations due to processes accompanying nucleosynthesis (i.e., meteorite studies) and ore formation. In the last decade however, advances in mass spectrometry technology have allowed the detection and quantification of minute, naturally occurring variations in the ratios of the stable isotopes of iron. Much of this work has been driven by the Earth and planetary science communities, although applications to biological and industrial systems are beginning to emerge.

⁵⁴Fe is observationally stable, but theoretically can decay to ⁵⁴Cr, with a half-life of more than 3.1x10²² years via double electron capture (εε).

The isotope ⁵⁶Fe is the isotope with the lowest mass per nucleon, 930.412 MeV/c², though not the isotope with the highest nuclear binding energy per nucleon, which is nickel-62. However, because of the details of how nucleosynthesis works, ⁵⁶Fe is a more common endpoint of fusion chains inside extremely massive stars and is therefore more common in the universe, relative to other metals, including ⁶²Ni, ⁵⁸Fe and ⁶⁰Ni, all of which have a very high binding energy.

The isotope ⁵⁷Fe is widely used in Mössbauer spectroscopy and the related nuclear resonance vibrational spectroscopy due to the low natural variation in energy of the 14.4 keV nuclear transition. The transition was famously used to make the first definitive measurement of gravitational redshift, in the 1960 Pound-Rebka experiment.

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